850-60-2Relevant academic research and scientific papers
The Influence of Substituents on the Nucleophilic Cleavage of the SiSi Linkage in Disilane Derivatives
Hengge, Edwin,Krysl, Franz Josef
, p. 731 - 742 (1981)
The rate constants of the SiSi cleavage with elementary bromine were measured in phenylmethyl- and pF-phenyl-methyldisilane derivatives.The influence of the substituents on the cleavage is discussed. - Keywords: Disilanederivatives; Rate constants, influence of substituents; SiSi-linkage
The Mechanism of the Reaction of Molecular Bromine with Organosilicon Hydrides
El-Durini, Nabil M. K.,Jackson, Richard A.
, p. 1275 - 1278 (2007/10/02)
The kinetics of the bromination of 7 triarylsilanes and 14 other organosilicon hydrides by molecular bromine in CCl4 have been determined by the stopped flow method.For triethylsilane, Arrhenius parameters have been measured in octane and CCl4, and solvent effects determined in other solvents of different polarity.The results accord with a molecular mechanism involving one molecule of bromine and one of the organosilicon hydride, with partial positive charge build-up on silicon in the transition state.
