The Influence of Substituents on the Nucleophilic Cleavage of the SiSi Linkage in Disilane Derivatives

DOI: 10.1007/BF00899776

Source and publish data:

Monatshefte fur Chemie p. 731 - 742 (1981)

Update date:2022-07-29

Topics:

Authors:

Hengge, Edwin

Krysl, Franz Josef

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1007/BF00899776

The rate constants of the SiSi cleavage with elementary bromine were measured in phenylmethyl- and pF-phenyl-methyldisilane derivatives.The influence of the substituents on the cleavage is discussed. - Keywords: Disilanederivatives; Rate constants, influence of substituents; SiSi-linkage

Full text of DOI:10.1007/BF00899776

Products guided by the article

Product name:Brom-tris-<4-fluor-phenyl>-silan

Cas No:850-60-2

R&D Labs maybe for 850-60-2

EGBERT CORPORATION

Contact:+86 18616952870

Address:Area
Jinhua City Mingzhu Pharmaceutical Co.,Ltd.

Contact:15857995878 0579-82207761

Address:No.169 Shenze Road, New Area,Jinpan Development Zone, Jinhua
Reliable Pharma Technology (Shanghai) Co., Ltd.

Contact:0086-21-67676847-8008

Address:Lane 1500, No.68, Xinfei Road, Songjiang District, Shanghai, 201611, P.R.China.
Jinan Finer Chemical Co., Ltd

website:https://www.finerchem.com

Contact:+86-531-88989536

Address:New Material Industrial Park, Jinan City, China
Kraeber & Co GmbH

Contact:+49-4101-3053-0

Address:Waldhofstrasse 14 ,25474 Ellerbek Germany

Relevant to this article

Bis(aminopyrrolidine)-derived ureas (APUs) as potent MCH₁ receptor antagonists

Doi:10.1016/j.bmcl.2004.12.036
(2005)
SYNTHESIS OF MACROLIDE ANTIBIOTICS. COMMUNICATION 2. SYNTHESIS OF THE C⁹-C¹³ FRAGMENT OF ERYTHRONOLIDES A AND C AND MEGALONOLIDE

Doi:10.1007/BF00958405
(1982)
Indirect electrochemical oxidation of cyclic ketones: Strong influence of ring size on the result of the reaction

Doi:10.1016/0040-4039(96)01177-X
(1996)
Synthesis and activity of tryptophan sulfonamide derivatives as novel non-hydroxamate TNF-α converting enzyme (TACE) inhibitors

Doi:10.1016/j.bmc.2009.04.033
(2009)
THE HIGHLY SELECTIVE REACTION OF LITHIUM DITHIOESTER ENOLATES WITH β-ALKENYL-β-PROPIOLACTONES: A SIMPLE METHOD FOR THE SYNTHESIS OF 6-(METHYLTHIO)THIOCARBONYL-(E)-3-ALKENOIC ACIDS

Doi:10.1246/cl.1983.1901
(1983)
Synthesis of the C8-C20 and C21-C30 segments of pectenotoxin 2

Doi:10.1016/j.tetlet.2007.04.136
(2007)

Article Doi