850164-44-2Relevant academic research and scientific papers
Synthesis of macrocycles via cobalt-mediated [2 + 2 + 2] cycloadditions
Bonaga, Llorente V. R.,Zhang, Han-Cheng,Moretto, Alessandro F.,Ye, Hong,Gauthier, Diane A.,Li, Jian,Leo, Gregory C.,Maryanoff, Bruce E.
, p. 3473 - 3485 (2005)
We investigated the formation of macrocycles from α,ω-diynes in cobalt-mediated co-cyclotrimerization reactions. Long-chain α,ω-diynes underwent metal-mediated [2 + 2 + 2] cycloadditions with nitriles, cyanamides, or isocyanates in the presence of CpCo(CO
