85020-93-5Relevant articles and documents
Chiral Bis(oxazoline) Ligands as C2-Symmetric Chiral Auxiliaries for the Synthesis of Enantiomerically Pure Bis-Cyclometalated Rhodium(III) Complexes
Grell, Yvonne,Demirel, Nemrud,Harms, Klaus,Meggers, Eric
, p. 3852 - 3859 (2019)
The synthesis of enantiomerically pure bis-cyclometalated rhodium(III) complexes using chiral bis(oxazoline) ligands as C2-symmetric chiral auxiliaries is described. Bis(oxazolines) are versatile chiral ligands for asymmetric catalysis but have
Chiral-at-Rhodium Catalyst Containing Two Different Cyclometalating Ligands
Grell, Yvonne,Hong, Yubiao,Huang, Xiaoqiang,Mochizuki, Takuya,Xie, Xiulan,Harms, Klaus,Meggers, Eric
supporting information, p. 3948 - 3954 (2019/11/14)
A method for the synthesis of a bis-cyclometalated rhodium complex containing two different cyclometalating ligands is reported and applied to asymmetric catalysis. The preparation of this previously inaccessible class of tris-heteroleptic bis-cyclometala