850262-93-0Relevant academic research and scientific papers
A highly stable, Au/Ru heterobimetallic photoredox catalyst with a [2.2]paracyclophane backbone
Knoll, Daniel M.,Zippel, Christoph,Hassan, Zahid,Nieger, Martin,Weis, Patrick,Kappes, Manfred M.,Br?se, Stefan
, p. 17704 - 17708 (2019)
We report the synthesis and catalytic application of a highly stable distance-defined Au/Ru heterobimetallic complex. [2.2]Paracyclophane serves as a backbone, holding the two metal centers in a spatial orientation and metal-metal fixed distance. The Au/Ru heterobimetallic complex is highly stable, easily accessible and exhibits promising catalytic activity in a visible-light mediated dual Au/Ru Meyer-Schuster rearrangement.
Metal-to-Metal Distance Modulated Au(I)/Ru(II) Cyclophanyl Complexes: Cooperative Effects in Photoredox Catalysis
Bizzarri, Claudia,Br?se, Stefan,Diller, Rolf,Hassan, Zahid,Israil, Roumany,Kappes, Manfred M.,Nieger, Martin,Riehn, Christoph,Schüssler, Lars,Schneider, Erik K.,Weis, Patrick,Zippel, Christoph
, p. 15187 - 15200 (2021/11/01)
The modular synthesis of Au(I)/Ru(II) decorated mono- and heterobimetallic complexes with π-conjugated [2.2]paracyclophane is described. [2.2]Paracyclophane serves as a rigid spacer which holds the metal centers in precise spatial orientations and allows
Synthesis of planar chiral pseudo-ortho-substituted aryl[2.2] paracyclophanes by stepwise successive palladium-catalyzed coupling reactions
Kitagaki, Shinji,Ohta, Yuu,Tomonaga, Shoichirou,Takahashi, Ryohei,Mukai, Chisato
experimental part, p. 986 - 991 (2011/09/20)
Planar chiral aryl[2.2]paracyclophanyl-thioureas and -phosphine with a pseudo-ortho substitution pattern have been designed and efficiently synthesized by stepwise successive palladium-catalyzed cross-coupling reactions.
