Dalton Transactions p. 17704 - 17708 (2019)
Update date:2022-09-26
Topics:
Knoll, Daniel M.
Zippel, Christoph
Hassan, Zahid
Nieger, Martin
Weis, Patrick
Kappes, Manfred M.
Br?se, Stefan
We report the synthesis and catalytic application of a highly stable distance-defined Au/Ru heterobimetallic complex. [2.2]Paracyclophane serves as a backbone, holding the two metal centers in a spatial orientation and metal-metal fixed distance. The Au/Ru heterobimetallic complex is highly stable, easily accessible and exhibits promising catalytic activity in a visible-light mediated dual Au/Ru Meyer-Schuster rearrangement.
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