85028-88-2Relevant academic research and scientific papers
Preparation and properties of fluorenylidene(phenyl)phosphines bearing bulky groups with electron-donating substituents in the ortho position on the phenyl group
Kawasaki, Subaru,Fujita, Takuma,Toyota, Kozo,Yoshifuji, Masaaki
, p. 1082 - 1090 (2007/10/03)
Huorenylidene(phenyl)phosphines having bulky substituents with an electron-donating group in the o-position on the phenyl group were prepared and their properties were compared. The prepared materials included 2,4-di-t-butyl-6-methoxyphenyl, 2,4-di-t-buty
Contributions to the Chemistry of Phosphorus,184. - Existence and Properties of a Phosphinidenediphosphirane (R1P)2C=PR2
Baudler, Marianne,Simon, Joachim
, p. 281 - 286 (2007/10/02)
The reaction of K(tBu)P-P(tBu)K with the (dichloromethylene)phosphane 2,4-tBu2-6-MeC6H2P=CCl2 (1) yields the first phosphinidenediphosphirane (tBuP)2C=P-(2,4-tBu2-6-Me-C6H2) (2).Further products are the cyclophosphanes (tBuP)n (n=3,4) as well as the phosp
