85029-00-1

Basic information

• Product Name: (4R,6R)-2-cyclohexyl-4,6-dimethyl-1,3-dioxane
• Synonyms: (4R,6R)-2-cyclohexyl-4,6-dimethyl-1,3-dioxane
• CAS NO: 85029-00-1
• Molecular Weight: 198.305
• Mol File: 85029-00-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (4R,6R)-2-cyclohexyl-4,6-dimethyl-1,3-dioxane(CAS DataBase Reference)
• NIST Chemistry Reference: (4R,6R)-2-cyclohexyl-4,6-dimethyl-1,3-dioxane(85029-00-1)
• EPA Substance Registry System: (4R,6R)-2-cyclohexyl-4,6-dimethyl-1,3-dioxane(85029-00-1)

Safety Data

• Hazardous Substances Data: 85029-00-1(Hazardous Substances Data)

Upstream product

• 42075-32-1 (2R,4R)-pentanediol 
• 2043-61-0 cyclohexanecarbaldehyde 

Downstream Products

• 93548-30-2 (2R,4R)-4-(1-Cyclohexyl-pentyloxy)-pentan-2-ol 
• 93548-30-2 (1S,1'R,3'R)-1-cyclohexyl-1-(3'-hydroxy-1'-methylbutoxy)pentane 
• 97949-92-3 (1R,1'R,3'R)-1-cyclohexyl-1-(3'-hydroxy-1'-methylbutoxy)pentane 
• 94340-20-2 (2R,4R)-4-(1-Cyclohexyl-3-methyl-but-3-enyloxy)-pentan-2-ol 
• 94340-20-2 (2R,4R)-4-((S)-1-Cyclohexyl-3-methyl-but-3-enyloxy)-pentan-2-ol 
• 94340-20-2 (2R,4R)-4-((R)-1-Cyclohexyl-3-methyl-but-3-enyloxy)-pentan-2-ol 
• 88764-87-8 (1S,1'R,3'R)-1-cyclohexyl-1-(3'-hydroxy-1'-methylbutoxy)ethane 
• 88726-10-7 (1R,1'R,3'R)-1-cyclohexyl-1-(3'-hydroxy-1'-methylbutoxy)ethane 
• 137250-91-0 (2R,4S)-4-((R)-1-Cyclohexyl-2-methylene-but-3-enyloxy)-pentan-2-ol 
• 137104-11-1 (R)-1-cyclohexyl-2-methylenebut-3-en-1-ol 
• 173398-01-1 (S)-1-cyclohexyl-2-methylenebut-3-en-1-ol 
• 94340-24-6 (4S)-4-cyclohexyl-4-hydroxy-2-methylbut-1-ene 
• 151453-08-6 (1R)-1-cyclohexyl-3-methylbut-3-en-1-ol 
• 63126-49-8 (R)-(+)-1-cyclohexylpentanol 

Relevant articles and documents

Assymmetric Synthesis via Acetal Templates. 3. On the Stereochemistry Observed in the Cyclization of Chiral Acetals of Polyolefinic Aldehydes: Formation of Optically Active Homoallylic Alcohols

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Nucleophilic cleavage of acetals using organometallic reagents

A highly chemo- and stereo-selective cleavage of acetals derived from (-)(2R,4R)-2,4-pentanediol with organoaluminum and organotitanium reagents has been demonstrated. The reactions proceed under mild conditions with excellent yields and high chemoselectivities to give, after removal of the auxiliary, chiral alcohols of high enantiomeric purities.

ASYMMETRIC SYNTHESIS via CHIRAL ACETAL TEMPLATES. 8. REACTIONS WITH ORGANOMETALLIC REAGENTS

The titanium tetrachloride catalyzed coupling of organometallic reagents with chiral acetals 1 is shown to provide a convenient route for the preparation of a variety of chiral alcohols 4 of high optical purity.