85029-27-2Relevant academic research and scientific papers
Oxidant controlled Pd-catalysed selective oxidation of primary alcohols
Liu, Chao,Tang, Shan,Lei, Aiwen
, p. 1324 - 1326 (2013)
The oxidant controlled palladium catalysed selective oxidation of primary alcohols to aldehydes or esters was investigated. The electronic properties of the benzylic alcohols and the structure of the oxidant are both important factors in controlling the selectivity between aldehydes and esters. A covalent benzyl ligand derived from BnCl provides η3 coordination to the Pd centre. This covalent ligand is the key to the selective oxidative esterification of primary alcohols.
Selective Actinide-Catalyzed Tandem Proton-Transfer Esterification of Aldehydes with Alcohols for the Production of Asymmetric Esters
Liu, Heng,Eisen, Moris S.
supporting information, p. 1461 - 1464 (2017/04/28)
Actinide-catalyzed tandem proton-transfer esterification between aldehydes and alcohols is presented herein for the first time. It represents a novel convenient and external-oxidant-free methodology in the preparation of asymmetric ester compounds. Various kinds of aldehydes and alcohols can be applied to this reaction, affording the corresponding ester product in moderate to high yields. A plausible mechanism was proposed on the basis of the kinetic, stoichiometric, and deuterium-labeling studies.
The collision induced loss of carbon monoxide from deprotonated benzyl benzoate in the gas phase. an anionic 1,2-Wittig type rearrangement
Chia, C.S. Brian,Taylor, Mark S.,Dua, Suresh,Blanksby, Stephen J.,Bowie, John H.
, p. 1435 - 1441 (2007/10/03)
The ion PhCO2--CHPh, upon collision activation, undergoes competitive losses of CO and CO2 of which the former process produces the base peak of the spectrum. Product ion and substituent effect (Hammett) studies indicate t
Pyrolytic Chemistry of Benzyl Benzoate
Chen, Ping-Shu,Chou, Chin-Hsing
, p. 597 - 600 (2007/10/03)
Flash vacuum pyrolysis of benzyl benzoate (3) at temperatures in the range 750-900 deg C and at 10-2 torr gave diphenylmethane (5) as the major product with toluene (6) and eight other trace products, namely biphenyl (7), dibenzyl (8), 2-, 3-, 4-phenyltoluenes (9, 10, 11, respectively), fluorene (12), benzyl alcohol (4) and benzaldehyde (13).The mechanism of formation of these products is proposed to involve benzyl and phenyl radicals. - Key Words Furfuryl benzoate; Benzyl benzoate; Flash vacuum pyrolysis.
Lithium Tungsten Dioxide Promoted Claisen-Tishchenko Condensation of Aromatic and Aliphatic Aldehydes
Villacorta, Gilberto M.,Filippo, Joseph San
, p. 1151 - 1154 (2007/10/02)
Lithium tungsten dioxide, LiWO2, has been shown to be a useful catalyst for effecting the Claisen-Tishchenko condensation of aldehydes under heterogeneous conditions.
