85040-50-2Relevant academic research and scientific papers
DIE PHOTOCHEMISCHE UMSETZUNG VON RMn(CO)5 (R = H, C6H5, CH2C6H5) MIT 1,3-BUTADIEN UND 1,3-PENTADIEN. INSERTION VON OLEFINEN IN Mn-C-BINDUNGEN
Lipps, Wolfgang,Kreiter, Cornelius G.
, p. 185 - 200 (2007/10/02)
Irradiation of C6H5CH2Mn(CO)5 in the presence of 1,3-pentadiene gives the unstable compound cis-C6H5CH2Mn(CO)4(η2-C5H8).Thermally, the η2-C5H8 ligand is inserted into the Mn-C bond of the benzyl group and Mn(CO)4(η3-C6H10C
