593-88-4Relevant articles and documents
Price,Richard
, p. 3209,3210 (1970)
Highly efficient synthesis of trimethylarsine
Gavrilenko,Chekulaeva,Pisareva
, p. 2018 - 2019 (1996)
A convenient, highly efficient, and environmentally safe procedure for the preparation of trimethylarsine was proposed. A quantitative yield of this compound in the reaction of As2O3 with AlMe3 was attained for the first time by using mechanochemical activation of the process.
Claeys
, p. 446,449 (1966)
Synthesis of a Homologous Series of Trialkyl Arsines (C3-C12) and Applications of Arsenic Triiodide as a Synthetic Precursor
Ligiéro, Carolina B.P.,Francisco, Marcos A.S.,Gama, Michelle S.,Carbonezi, Carlos A.,Leocadio, Isabela C.L.,de Souza, Wladmir F.,Esteves, Pierre M.
, p. 912 - 916 (2021/03/17)
This work presents some modifications in the post-synthetic processing for a classical arsenic reagent: AsI3. In comparison with the widely used analog, the trichloride, arsenic triiodide presents several advantages such as low toxicity, air stability, and low volatility. It was used as a synthetic precursor in the preparation of a variety of arsenic(III) derivatives like arsines, arsenites, and thioarsenites. Besides that, AsI3 was submitted to a diversity-oriented Grignard reaction in the preparation of a homologous series of trialkyl arsines ranging from AsC3H9 to AsC12H27. The series was analyzed by comprehensive two-dimensional gas chromatography coupled with time-of-flight mass spectrometry to provide a trialkyl arsines library that can be used for the direct analysis of natural samples.
Trialkyl Group VA metal compounds
-
, (2008/06/13)
Disclosed are methods of preparing trialkyl Group VA metal compounds in high yield and high purity. Such trialkyl Group VA metal compounds are substantially free of oxygenated impurities, ethereal solvents and metallic impurities.
