850534-25-7

Upstream product

• 499157-71-0 2-[(tri-n-butylstannyl)methyl]-3-chloro-1-propene 
• 159572-27-7 (R)-2-((benzyloxy)methoxy)propanal 

Downstream Products

• 850534-31-5 1-[(6-{(1R)-1-[(4-methoxyphenyl)methoxy]-2-(1,1,2,2-tetramethyl-1-silapropoxy)ethyl}(4S,6R)-2,2-dimethyl(1,3-dioxan-4-yl))methyl](1R,2R)-2-[(phenylmethoxy)methoxy]propyl 2,2-dimethylpropanoate 
• 850534-42-8 1-[(6-{(1R)-1-[(4-methoxyphenyl)methoxy]-2-(1,1,2,2-tetramethyl-1-silapropoxy)ethyl}(4R,6R)-2,2-dimethyl(1,3-dioxan-4-yl))methyl](1R,2R)-2-[(phenylmethoxy)methoxy]propyl 2,2-dimethylpropanoate 
• 850534-27-9 (1R,5R,6R)-1-{(1R)-1-[(phenylmethoxy)methoxy]ethyl}-5-hydroxy-6-[(4-methoxyphenyl)methoxy]-3-methylene-7-(1,1,2,2-tetramethyl-1-silapropoxy)heptyl 2,2-dimethylpropanoate 
• 850534-41-7 (1R,3R,5R,6R)-1-{(1R)-1-[(phenylmethoxy)methoxy]ethyl}-3,5-dihydroxy-6-[(4-methoxyphenyl)methoxy]-7-(1,1,2,2-tetramethyl-1-silapropoxy)heptyl 2,2-dimethylpropanoate 
• 850534-30-4 (1R,3S,5R,6R)-1-{(1R)-1-[(phenylmethoxy)methoxy]ethyl}-3,5-dihydroxy-6-[(4-methoxyphenyl)methoxy]-7-(1,1,2,2-tetramethyl-1-silapropoxy)heptyl 2,2-dimethylpropanoate 
• 850534-29-1 (1R,5R,6R)-1-{(1R)-1-[(phenylmethoxy)methoxy]ethyl}-5-hydroxy-6-[(4-methoxyphenyl)methoxy]-3-oxo-7-(1,1,2,2-tetramethyl-1-silapropoxy)heptyl 2,2-dimethylpropanoate 
• 850534-33-7 (1R,2R)-1-[(6-{(1S)-1-[(4-methoxyphenyl)methoxy]-3,3-dimethyl-2-oxopent-4-enyl}(4S,6R)-2,2-dimethyl(1,3-dioxan-4-yl))methyl]-2-[(phenylmethoxy)methoxy]propyl 2,2-dimethylpropanoate 
• 850534-43-9 1-(6-{(1R)-1-[(4-methoxyphenyl)methoxy]-2-(1,1,2,2-tetramethyl-1-silapropoxy)ethyl}(4S,6R)-2,2-dimethyl(1,3-dioxan-4-yl))(2R,3R)-3-[(phenylmethoxy)methoxy]butan-2-ol 
• 850534-32-6 1-[(6-{(1R)-2-hydroxy-1-[(4-methoxyphenyl)methoxy]ethyl}(4S,6R)-2,2-dimethyl(1,3-dioxan-4-yl))methyl](1R,2R)-2-[(phenylmethoxy)methoxy]propyl 2,2-dimethylpropanoate 
• 850534-35-9 (1R,2R)-1-{[(6S)-6-(1,1-dimethylprop-2-enyl)-6-methoxy-5-oxo(2,3,4,5-tetrahydropyran-2-yl)]methyl}-2-[(phenylmethoxy)methoxy]propyl 2,2-dimethylpropanoate 
• 850534-36-0 methyl 2-(6-{(2R,3R)-2-(2,2-dimethylpropanoyloxy)-3-[(phenylmethoxy)methoxy]butyl}(2S)-2-(1,1-dimethylprop-2-enyl)-2-methoxy-3-oxo-5,6-dihydro-2H-pyran-4-ylidene)acetate 
• 850534-34-8 (1R,2R)-1-{[(6S)-6-(1,1-dimethylprop-2-enyl)-6-methoxy-5-oxo(3,4,5,6-tetrahydro-2H-pyran-2-yl)]methyl}-2-[(phenylmethoxy)methoxy]propyl 2,2-dimethylpropanoate 

Relevant academic research and scientific papers

Enantio- and diastereoselective additions to aldehydes using the bifunctional reagent 2-(chloromethyl)-3-(tributylstannyl)propene: Application to a synthesis of the C16-C27 segment of bryostatin 1

(Chemical Equation Presented) Reactions of the bifunctional allylstannane 2-(chloromethyl)-3-(tributylstannyl)propene with aldehydes have been examined. These generally occur in high yields using Lewis acid promoters and the products can be isolated and p