850609-33-5

Basic information

• Product Name: [PdBr(2-(diphenylphosphino)aminotriazole-P)(2-(diphenylphosphino)aminothiazole-P,N)][Br]
• CAS NO: 850609-33-5
• Molecular Weight: 834.871
• Mol File: 850609-33-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [PdBr(2-(diphenylphosphino)aminotriazole-P)(2-(diphenylphosphino)aminothiazole-P,N)][Br](CAS DataBase Reference)
• NIST Chemistry Reference: [PdBr(2-(diphenylphosphino)aminotriazole-P)(2-(diphenylphosphino)aminothiazole-P,N)][Br](850609-33-5)
• EPA Substance Registry System: [PdBr(2-(diphenylphosphino)aminotriazole-P)(2-(diphenylphosphino)aminothiazole-P,N)][Br](850609-33-5)

Safety Data

• Hazardous Substances Data: 850609-33-5(Hazardous Substances Data)

Upstream product

• 304476-02-6 N-(diphenylphosphino)thiazol-2-amine 
• 12145-47-0 cis-dibromo-(cyclooctadiene)palladium(II) 

Relevant articles and documents

Investigating the effects of steric hindrance on the coordination of 2-aminothiazoyl based ligands

The ligands 2-(diphenylphosphino)aminothiazole (dppat) 2- (diphenylphosphino)amino-4-methylthiazole (Medppat) and 2-(diphenylphosphino) amino-4-tert-butylthiazole (Budppat) have been prepared. Reaction of these ligands with MCl2 (COD) gives [MCl(dppat-P,N)(dppat-P)][Cl], [MCl(Medppat-P,N)(Medppat-P)][Cl], and [PtCl2 (tBu-dppat- P2], respectively. The increased bulk at the 4-position limits the formation of a P, N system in Budppat. The X-ray structure of [PtCl(Medppat-P,N)(Medppat-P)][Cl] reveals that the monodentate ligand has undergone a tautomerism upon coordination.