850617-97-9Relevant academic research and scientific papers
Iron-Catalyzed Asymmetric Decarboxylative Azidation
Wang, Kaikai,Li, Yajun,Li, Xiaoyan,Li, Daliang,Bao, Hongli
supporting information, p. 8847 - 8851 (2021/11/24)
The first iron-catalyzed asymmetric azidation of benzylic peresters has been reported with trimethylsilyl azide (TMSN3) as the azido source. Hydrocarbon radicals that lack of strong interactions were capable to be enantioselectively azidated. The reaction features good functional group tolerance, high yields, and mild conditions. The chiral benzylic azides can further be used in click reaction, phosphoramidation, and reductive amination, which demonstrate the synthetic values of this reaction.
Secondary amino-and cycloamino-cycloalkanol derivatives and methods of their use
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Page/Page column 81-82, (2010/02/14)
The present invention is directed to secondary amino- and cycloamino-cycloalkanol derivatives, compositions containing these derivatives, and methods of their use for the prevention and treatment of conditions ameliorated by monoamine reuptake including,
