850705-03-2

Upstream product

• 135351-89-2 2,4,6-tris(benzyloxy)benzaldehyde 
• 850705-00-9 5-bromo-{3-[2-(tert-butyldimethylsilanyloxy)ethyl]-4,6-bis(methoxymethoxy)-2,3-dihydrobenzofuran-2-yloxy}triisopropylsilane 
• 850704-98-2 5-[[1-(R,S)-{2',4',6'-tris(O-benzyl)}-1-hydroxymethyl]-3-[2-(t-butyldimethylsilyloxy)ethyl]-4,6-bis(O-methoxymethyl)-2,3-dihydrobenzofuran-2-yloxy]triisopropylsilane 

Downstream Products

• 850705-09-8 5-keto-[[2',4',6'-tris(O-benzyl)phenyl]-3-[2-(t-butyldimethylsilyloxy)ethyl]-4,6-bis(O-benzyl)-2,3-dihydrobenzofuran-2-yloxy]triisopropylsilane 
• 850705-11-2 (4,6-bis-benzyloxy-2,3,3a,8a-tetrahydro-1,8-dioxa-cyclopenta[a]inden-5-yl)-(2,4,6-tris-benzyloxy-phenyl)-methanone 

Relevant academic research and scientific papers

Ordering the reductive and cytochrome P450 oxidative steps in demethylsterigmatocystin formation yields general insights into the biosynthesis of aflatoxin and related fungal metabolites

The biosynthesis of the potent environmental carcinogen aflatoxin B1 involves ca. 15 steps beyond the first polyketide intermediate. Central among these is the rearrangement of the anthraqinone versicolorin A to the xanthone demethylsterigmatocystin. Gene