135351-89-2

Basic information

• Product Name: Benzaldehyde, 2,4,6-tris(phenylmethoxy)-
• CAS NO: 135351-89-2
• Molecular Formula: C28H24O4
• Molecular Weight: 424.496
• Mol File: 135351-89-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzaldehyde, 2,4,6-tris(phenylmethoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzaldehyde, 2,4,6-tris(phenylmethoxy)-(135351-89-2)
• EPA Substance Registry System: Benzaldehyde, 2,4,6-tris(phenylmethoxy)-(135351-89-2)

Safety Data

• Hazardous Substances Data: 135351-89-2(Hazardous Substances Data)

Upstream product

• 59434-20-7 1,3,5-tri-O-benzylphloroglucinol 
• 68-12-2 N,N-dimethyl-formamide 
• 108-73-6 3,5-dihydroxyphenol 
• 100-39-0 benzyl bromide 
• 487-70-7 2,4,6-trihydroxybenzaldehyde 
• 100-51-6 benzyl alcohol 

Downstream Products

• 135378-25-5 C₁₂₈H₁₀₂N₄O₁₂ 
• 850704-98-2 5-[[1-(R,S)-{2',4',6'-tris(O-benzyl)}-1-hydroxymethyl]-3-[2-(t-butyldimethylsilyloxy)ethyl]-4,6-bis(O-methoxymethyl)-2,3-dihydrobenzofuran-2-yloxy]triisopropylsilane 
• 95733-02-1 daphnodorin B 
• 1453207-48-1 ((2R,3S)-3-(benzyloxy)-5-methoxy-2,8-bis(4-methoxyphenyl)-3,4-dihydro-2H-furo[2,3-h]chromen-9-yl)(2,4,6-tris(benzyloxy)phenyl)methanone 
• 1453207-33-4 (2-(4-methoxyphenyl)-5-methylbenzofuran-3-yl)(2,4,6-tris(benzyloxy)phenyl)methanone 
• 1453207-20-9 3-(4-methoxyphenyl)-1-(2,4,6-tri(benzyloxy)phenyl)prop-2-yn-1-one 
• 850705-09-8 5-keto-[[2',4',6'-tris(O-benzyl)phenyl]-3-[2-(t-butyldimethylsilyloxy)ethyl]-4,6-bis(O-benzyl)-2,3-dihydrobenzofuran-2-yloxy]triisopropylsilane 
• 850705-03-2 5-keto-[[2',4',6'-tris(O-benzyl)phenyl]-3-[2(t-butyldimethylsilyloxy)ethyl]-4,6-bis(O-methoxymethyl)-2,3-dihydrobenzofuran-2-yloxy]triisopropylsilane 
• 850705-11-2 (4,6-bis-benzyloxy-2,3,3a,8a-tetrahydro-1,8-dioxa-cyclopenta[a]inden-5-yl)-(2,4,6-tris-benzyloxy-phenyl)-methanone 

Relevant articles and documents

Construction of 2-substituted-3-functionalized benzofurans via intramolecular heck coupling: Application to enantioselective total synthesis of daphnodorin B

A novel approach was developed for the synthesis of 2-substituted-3- functionalized benzofurans, using an intramolecular Heck reaction which was further applied in the first enantioselective total synthesis of Daphnodorin B.

Synthesis of facially-encumbered porphyrins. An approach to light-harvesting antenna complexes

2,6-di- and 2.4.6-tri-benzyloxybenzaldehydes are converted to the respective octa- and dodeca-benzyloxy porphyrins in 9-52% yields via the two-step one-flask room-temperature porphyrin synthesis.