850804-93-2

Basic information

• Product Name: [(Ni(CO)3)2((C₆H₅)2Sb(CH₂)3Sb(C₆H₅)2)]
• Synonyms: [(Ni(CO)3)2((C₆H₅)2Sb(CH₂)3Sb(C₆H₅)2)]
• CAS NO: 850804-93-2
• Molecular Weight: 879.446
• Mol File: 850804-93-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(Ni(CO)3)2((C₆H₅)2Sb(CH₂)3Sb(C₆H₅)2)](CAS DataBase Reference)
• NIST Chemistry Reference: [(Ni(CO)3)2((C₆H₅)2Sb(CH₂)3Sb(C₆H₅)2)](850804-93-2)
• EPA Substance Registry System: [(Ni(CO)3)2((C₆H₅)2Sb(CH₂)3Sb(C₆H₅)2)](850804-93-2)

Safety Data

• Hazardous Substances Data: 850804-93-2(Hazardous Substances Data)

Upstream product

• 603-36-1 triphenylantimony 
• 38611-86-8 1,3-bis(diphenylstibino)propane 
• 13463-39-3 tetracarbonyl nickel 

Relevant articles and documents

The transition metal carbonyl complexes of 1,3-bis(di-R-stibino)propanes (R = Me or Ph)

The synthesis and characterisation of complexes of two distibinopropanes R2Sb(CH2)3SbR2 (R = Me or Ph) with a variety of metal carbonyls is described. These include cis-[M(CO) 4{R2Sb(CH2)3SbR2}] (M = Cr, Mo or W), [{Fe(CO)4}2{μ-R2Sb(CH 2)3SbR2}], [{Ni(CO)3} 2{μ-R2Sb(CH2)3SbR2}], [Co2(CO)6{Ph2Sb(CH2) 3SbPh2}], [Co2(CO)4{Me 2Sb(CH2)3SbMe2}3][Co(CO) 4]2 and [Mn2(CO)8{Ph 2Sb(CH2)3SbPh2}]. The complexes have been characterised by analysis, mass spectrometry, IR and multinuclear NMR spectroscopy as appropriate. Comparison of the spectroscopic data on these complexes with those of other stibine complexes and with complexes of Group 16 ligands has been used to establish the relative electronic properties of the distibines.