85098-22-2

Upstream product

• 85165-16-8 methyl <2S-<2α(S*),3β,6β>>-8-ethyl-α,3-dimethyl-5-oxo-1,7-dioxaspiro<5.5>undec-8-ene-2-acetate 
• 85165-17-9 methyl <2S-<2α(S*),3β,6α>>-8-ethyl-α,3-dimethyl-5-oxo-1,7-dioxaspiro<5.5>undec-8-ene-2-acetate 
• 85098-15-3 methyl <2S-<2α(S*),3β,6β>>-8-ethyl-α,3-dimethyl-5-methylene-1,7-dioxaspiro<5.5>undec-8-ene-2-acetate 
• 85165-30-6 methyl <2S-<2α(S*),3β,6α>>-8-ethyl-α,3-dimethyl-5-methylene-1,7-dioxaspiro<5.5>undec-8-ene-2-acetate 
• 85098-18-6 methyl <2S-<2α(S*),3β,5α,6α(S*)>>-8-ethyl-α,3,5-trimethyl-9-oxo-1,7-dioxaspiro<5.5>undecane-2-acetate 
• 85098-18-6 methyl <2S-<2α(S*),3β,5ξ,6β(S*)>>-8-ethyl-α,3,5-trimethyl-9-oxo-1,7-dioxaspiro<5.5>undecane-2-acetate 
• 85098-18-6 methyl <2S-<2α(S*),3β,5ξ,6β(R*)>>-8-ethyl-α,3,5-trimethyl-9-oxo-1,7-dioxaspiro<5.5>undec-8-ene-2-acetate 
• 85098-19-7 methyl <2S-<2α(S*),3β,5α,6β(S*)>>-8-ethyl-α,3,5-trimethyl-9-methylene-1,7-dioxaspiro<5.5>undecane-2-acetate 
• 85098-19-7 methyl <2S-<2α(S*),3β,5β,6β(S*)>>-8-ethyl-α,3,5-trimethyl-9-methylene-1,7-dioxaspiro<5.5>undecane-2-acetate 
• 85098-19-7 methyl <2S-<2α(S*),3β,5α,6α(S*)>>-8-ethyl-α,3,5-trimethyl-9-methylene-1,7-dioxaspiro<5.5>undecane-2-acetate 
• 85098-19-7 methyl <2S-<2α(S*),3β,5β,6α(S*)>>-8-ethyl-α,3,5-trimethyl-9-methylene-1,7-dioxaspiro<5.5>undecane-2-acetate 
• 85165-31-7 methyl <2S-<2α(S*),3β,5α,6α>>-8-ethyl-α,3,5-trimethyl-1,7-dioxaspiro<5.5>undec-8-ene-2-acetate 
• 85165-32-8 methyl <2S-<2α(S*),3β,5β,6α>>-8-ethyl-α,3,5-trimethyl-1,7-dioxaspiro<5.5>undec-8-ene-2-acetate 
• 85098-16-4 methyl <2S-<2α(S*),3β,5ξ,6β>>-8-ethyl-α,3,5-trimethyl-1,7-dioxaspiro<5.5>undec-8-ene-2-acetate 

Downstream Products

• 85098-27-7 methyl <2R-(2R*,3S*,4S*,6R*,7(RS)*,8E,10R*,11R*)>-11-(benzoyloxy)-3-<<(1,1-dimethylethyl)dimethylsilyl>oxy>-7-hydroxy-2,4,6,10-tetramethyl-8-tridecenoate 
• 85098-24-4 methyl <2R-(2R*,3S*,4S*,6R*,10R*,11R*)>-11-(benzoyloxy)-3-<<(1,1-dimethylethyl)dimethylsilyl>oxy>-2,4,6,10-tetramethyl-7-oxotridecanoate 
• 85098-26-6 methyl <2R-(2R*,3S*,4S*,6R*,8E,10R*,11R*)>-11-(benzoyloxy)-3-<<(1,1-dimethylethyl)dimethylsilyl>oxy>-2,4,6,10-tetramethyl-7-oxo-8-tridecenoate 
• 81644-19-1 10-deoxymethynolide 
• 85098-23-3 Benzoic acid (1R,2R)-4-{2-[(1R,3S,4S,5R)-4-(tert-butyl-dimethyl-silanyloxy)-5-methoxycarbonyl-1,3-dimethyl-hexyl]-[1,3]dithiolan-2-yl}-1-ethyl-2-methyl-butyl ester 

Relevant academic research and scientific papers

Macrolide Total Synthesis. The Synthesis of Seco-Acid Derivatives for the synthesis of Methymycin and 10-Deoxymethymycin

A stereoselective synthesis of the chiral seco-acid derivatives for the synthesis of methymycin and 10-deoxymethymycin from carbohydrate precursors is described.Additionally, a formal total synthesis of methymycin is achieved.The synthetic scheme proceeds