85137-57-1Relevant articles and documents
Photo-Induced ortho-C-H Borylation of Arenes through in Situ Generation of Rhodium(II) Ate Complexes
Araujo Dias, Ant?nio Junio,Nagashima, Yuki,Tanaka, Jin,Tanaka, Ken
supporting information, p. 11325 - 11331 (2021/08/03)
Photoinduced in situ "oxidation"of half-sandwich metal complexes to "high-valent"cationic metal complexes has been used to accelerate catalytic reactions. Here, we report the unprecedented photoinduced in situ "reduction"of half-sandwich metal [Rh(III)] complexes to "low-valent"anionic metal [Rh(II)] ate complexes, which facilitate ligand exchange with electron-deficient elements (diboron). This strategy was realized by using a functionalized cyclopentadienyl (CpA3) Rh(III) catalyst we developed, which enabled the basic group-directed room temperature ortho-C-H borylation of arenes.
Non-catalytic alkylation of phenol and aniline with 1-hydroxymethylpyrazole
Attaryan, H. S.,Rstakyan, V. I.,Hayotsyan, S. S.,Asratyan, G. V.
, p. 1319 - 1321,3 (2020/08/31)
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Antiarrhytmic benzylimidazole
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, (2008/06/13)
Benzylazole derivatives being useful as antiarrhythmic agent are obtained by reacting the corresponding 2,3-epoxypropyloxybenzylazole with a primary or secondary amine.
