851393-67-4

Upstream product

• 111-24-0 1,5-dibromo-pentane 
• 10602-01-4 p-bromobenzaldehyde 1,3-dioxolane 
• 93943-06-7 4-(methoxymethyl)benzaldehyde 
• 851393-55-0 2-(4-methoxymethylphenyl)-1,3-dimethylimidazolidine 

Downstream Products

• 930585-84-5 (4-{4-butyl-5-[4-(5-{4-[3-butyl-5-(4-hydroxymethyl-phenyl)-furan-2-yl]-phenyl}-pentyl)-phenyl]-furan-2-yl}-phenyl)-methanol 
• 930585-89-0 C₄₇H₄₈O₄ 
• 930585-79-8 C₄₉H₅₂O₆ 

Relevant academic research and scientific papers

A bridging double bond as an electron acceptor for optical nonlinearity of furan-containing [n.2]cyclophenes

All in the twist: Unusually large Stokes shifts and nonlinear optical properties are exhibited by furan-containing teraryl cyclophene derivatives (see picture). These cyclophenes have neither particularly strong electron-donating nor electron-withdrawing

Reductive lithiation of 1,3-dimethyl-2-arylimidazolidines

Naphthalene catalyzed lithiation of 1,3-dimethyl-2-phenylimidazolidine led to cleavage of the benzylic carbon-nitrogen bond, with formation of an intermediate dianion. Under similar conditions, 1,3-dimethyl-2-(4-chlorophenyl) imidazolidine underwent regioselective cleavage of the aromatic carbon-chlorine bond, leading to a 4-formylphenyllithium equivalent, whilst 1,3-dimethyl-2-(4- methoxymethylphenyl)imidazolidine underwent regioselective cleavage of the benzylic carbon-oxygen bond, leading to a 4-formylbenzyllithium equivalent.