851594-61-1Relevant articles and documents
Synthesis of functionalized salicylate esters and amides by photochemical acylation
Soltani, Omid,De Brabander, Jef K.
, p. 1696 - 1699 (2007/10/03)
(Chemical Equation Presented) Functionalized salicylates in a flash: Photolysis of functionalized benzodioxinones in the presence of alcohols or amines is a powerful method for the synthesis of sterically hindered salicylic esters and amides (see scheme). This reaction tolerates a broad range of functional groups and efficiently engages a wide range of acylation substrates, including sterically hindered nucleophiles that are inert to other acylation methods.