851625-43-9

Upstream product

• 903906-55-8 p–tolyl 2,3-O-isopropylidene-1-thio-α-L-rhammopyranoside 
• 108-24-7 acetic anhydride 
• 41632-89-7 isobutyraldehyde dimethyl acetal 
• 628308-75-8 (2S,3S,4R,5R,6S)-2-methyl-6-(p-tolylthio)tetrahydro-2H-pyranol 
• 77-76-9 2,2-dimethoxy-propane 

Downstream Products

• 1252047-38-3 p-methoxyphenyl 4-O-acetyl-2,3-O-isopropylidene-α-L-rhamnopyranosyl-(1->2)-3,4-O-isopropylidene-β-D-fucopyranoside 
• 1359721-35-9 p-methoxyphenyl 4-O-acetyl-2,3-O-isopropylidene-alpha-L-rhamnopyranosyl-(1->3)-4,6-O-benzylidene-2-deoxy-N-phthalimido-β-D-glucopyranoside 
• 1359721-42-8 p-methoxyphenyl 2-azido-4,6-O-benzylidene-2-deoxy-α-D-glucopyranosyl-(1->4)-2,3-O-isopropylidene-α-L-rhamnopyranosyl-(1->3)-2-deoxy-N-phthalimido-4,6-O-benzylidene-β-D-glucopyranoside 
• 1359721-40-6 p-methoxyphenyl 3-O-acetyl-2-azido-4,6-O-benzylidene-2-deoxy-α-D-glucopyranosyl-(1->4)-2,3-O-isopropylidene-α-L-rhamnopyranosyl-(1->3)-4,6-O-benzylidene-2-deoxy-N-phthalimido-β-D-glucopyranoside 
• 1359721-39-3 p-methoxyphenyl 2,3-O-isopropylidene-α-L-rhamnopyranosyl-(1->3)-4,6-O-benzylidene-2-deoxy-N-phthalimido-β-D-glucopyranoside 
• 1214256-05-9 C₄₀H₄₄O₁₅ 
• 943221-77-0 p-tolyl 4-O-acetyl-3-O-tert-butyldimethylsilyl-2-O-levulinoyl-1-thio-α-L-rhamnopyranoside 
• 943221-82-7 p-tolyl 4-O-acetyl-3-O-tert-butyldimethylsilyl-1-thio-α-L-rhamnopyranoside 
• 943221-75-8 p-tolyl 4-O-acetyl-2,3-O-isopropylidene-α-L-rhamnopyranosyl-(1->3)-2,4-di-O-acetyl-1-thio-α-L-rhamnopyranoside 
• 943221-88-3 dodecanyl 4-O-acetyl-3-O-(p-methoxybenzyl)-2-O-levulinoyl-α-L-rhamnopyranosyl-(1->4)-2,3-O-isopropylidene-α-L-rhamnopyranoside 
• 943221-78-1 p-tolyl 4-O-acetyl-3-O-(p-methoxybenzyl)-2-O-levulinoyl-1-thio-α-L-rhamnopyranoside 
• 943221-86-1 4-O-acetyl-3-O-(4-methoxy)benzyl-1-(4-tolyl)thio-α-L-rhamnopyranoside 
• 943221-81-6 p-tolyl 4-O-acetyl-1-thio-α-L-rhamnopyranoside 

Relevant academic research and scientific papers

Synthesis of a tetrasaccharide related to the triterpenoid saponin Bellisoside isolated from Bellis perennis (compositae)

A concise synthesis of a tetrasaccharide related to the triterpenoid saponins Bellisoside has been accomplished from commercially available monosaccharides through rational protecting group manipulations and stereoselective glycosylations. For the glycosylation reactions, H 2SO4-silica has been successfully used as an alternative to conventional Lewis acids such as TfOH or TMSOTf. The target tetrasaccharide has been synthesized in the form of its p-methoxyphenyl glycoside which leaves scope for further glyco-conjugate formation through the selective deprotection of p-methoxyphenyl glycoside followed by trichloroacetimidate chemistry.

Tandem one-pot acetalation-acetylation for direct access to differentially protected thioglycosides and O-glycosides with p-toluenesulfonic acid

A new tandem one-pot acetalation-acetylation procedure is reported which streamlines routine protecting-group manipulation of carbohydrate molecules in production of differentially protected O- and thioglycosides. This new procedure eliminates the use of

One-pot acetalation-acetylation of sugar derivatives employing perchloric acid immobilised on silica

Perchloric acid immobilised on silica gel has been used as an efficient promoter for per-O-acetylation, and acetalation and subsequent O-acetylation of glycosides and thioglycosides in one-pot using stoichiometric reagents.