851626-27-2

Upstream product

• 851682-47-8 (Z)-(S)-2-Methyl-4-(tetrahydro-pyran-2-yloxy)-pent-2-enoic acid ethyl ester 
• 76438-34-1 (S)-2-(tetrahydropyranyloxy)propanal 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 851626-25-0 (4S)-2-methyl-4-(tetrahydropyran-2'-yloxy)pent-2-en-1-ol 

Downstream Products

• 851626-46-5 (2RS,1'S,2'Z) 2-(4-methoxybenzyloxy)hex-5-enoic acid 4'-(tert-butyl(diphenyl)silyloxy)-1',3'-dimethylbut-2'-enyl ester 
• 851626-20-5 (2S,3Z)-5-(tert-butyl(diphenyl)silyloxy)-4-methylpent-3-en-2-ol 

Relevant academic research and scientific papers

Highly enantioselective sequential Claisen-Ireland/metathesis: Synthesis of cycloalkenes bearing two contiguous highly functionalized asymmetric centres

A sequence of two reactions, consisting of a highly stereoselective silylated ketene acetal Claisen-Ireland rearrangement followed by a ring closing metathesis, gave a stereocontrolled access to various carbocycles.