851660-03-2

Upstream product

• 705-31-7 4-trifluoromethylphenylacetylene 
• 274-07-7 benzo[1,3,2]dioxaborole 

Downstream Products

• 1034330-32-9 5,5-dimethyl-2-[2-(4-trifluoromethylphenyl)ethen-1-yl]-1,3,2-dioxaborinane 
• 918164-67-7 2,4-bis[4-(trifluoromethyl)phenyl]thiophene 
• 61637-11-4 (2E)-1-phenyl-3-[4-(trifluoromethyl)phenyl]prop-2-en-1-one 
• 1004651-40-4 (E)-1-(4-methylphenyl)-3-{(4-(trifluoromethyl)phenyl)}-2-propen-1-one 
• 1399078-85-3 C₂₃H₂₀F₃NO₂S 

Relevant academic research and scientific papers

Cu-catalyzed [2 + 2 + 1] cascade annulation of vinyl iodonium salts with elemental sulfur/selenium for the modular synthesis of thiophenes and selenophenes

A [2 + 2 + 1] annulation protocol has been established for the modular synthesis of 2,4-disubstituted thiophenes/selenophenes, with excellent regioselectivity. The reactions have been catalyzed by copper salt with elemental sulfur and selenium serving as

Copper(I)-catalyzed carboxylation of aryl- and alkenylboronic esters

(Chemical Equation Presented) The copper(I)-catalyzed carboxylation reaction of aryl- and alkenylboronic esters proceeded smoothly under CO 2 to give the corresponding carboxylic acid in good yield. This reaction showed wide generality with higher functional group tolerance compared to the corresponding Rh(I)-catalyzed reaction.