851662-59-4Relevant articles and documents
A synthesis of optically active α-quaternary α-amino acids and esters by assembling three components, ketones, (R)-chloromethyl p-tolyl sulfoxide, and sodium azide, via sulfinyloxiranes
Satoh, Tsuyoshi,Hirano, Mizue,Kuroiwa, Akio,Kaneko, Youhei
, p. 9268 - 9279 (2007/10/03)
Treatment of lithium α-sulfinyl carbanion of chloromethyl p-tolyl sulfoxides with ketones at low temperature afforded adducts in almost quantitative yields, which were exposed to t-BuOK to give sulfinyloxiranes in high yields. The sulfinyloxirane was reac
