851662-61-8

Basic information

• Product Name: 3'-(p-tolylsulfinyl)spiro[cyclopentadecane-1,2'-oxirane]
• Synonyms: 3'-(p-tolylsulfinyl)spiro[cyclopentadecane-1,2'-oxirane]
• CAS NO: 851662-61-8
• Molecular Weight: 376.604
• Mol File: 851662-61-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3'-(p-tolylsulfinyl)spiro[cyclopentadecane-1,2'-oxirane](CAS DataBase Reference)
• NIST Chemistry Reference: 3'-(p-tolylsulfinyl)spiro[cyclopentadecane-1,2'-oxirane](851662-61-8)
• EPA Substance Registry System: 3'-(p-tolylsulfinyl)spiro[cyclopentadecane-1,2'-oxirane](851662-61-8)

Safety Data

• Hazardous Substances Data: 851662-61-8(Hazardous Substances Data)

Upstream product

• 502-72-7 cyclopentadecanone 
• 24824-93-9 chloromethyl p-tolyl sulfoxide 
• 172467-95-7 1-[Chloro-(toluene-4-sulfinyl)-methyl]-cyclopentadecanol 

Downstream Products

• 913077-24-4 methyl 1-(benzylamino)cyclopentadecanecarboxylate 
• 913077-23-3 1-(benzylamino)cyclopentadecanecarbaldehyde 

Relevant articles and documents

A synthesis of optically active α-quaternary α-amino acids and esters by assembling three components, ketones, (R)-chloromethyl p-tolyl sulfoxide, and sodium azide, via sulfinyloxiranes

Treatment of lithium α-sulfinyl carbanion of chloromethyl p-tolyl sulfoxides with ketones at low temperature afforded adducts in almost quantitative yields, which were exposed to t-BuOK to give sulfinyloxiranes in high yields. The sulfinyloxirane was reac