85203-17-4Relevant academic research and scientific papers
Convenient Generation of Adamantylidenecarbene from (Bromomethylene)adamantane. An Efficient Method of Adamantylidenecyclopropanation
Sasaki, Tadashi,Eguchi, Shoji,Tanida, Masahiro,Nakata, Fumiyasu,Esaki, Toshiyuki
, p. 1579 - 1586 (1983)
Crown ether catalyzed dehydrobromination of ω-(bromomethylene)adamantane (2) with t-BuOK provided a convenient and efficient method of generation of adamantylidenecarbene (1).In the presence of an appropriate olefin, 1 gave the corresponding adamantyliden
