Journal of Organic Chemistry p. 1579 - 1586 (1983)
Update date:2022-08-04
Topics:
Sasaki, Tadashi
Eguchi, Shoji
Tanida, Masahiro
Nakata, Fumiyasu
Esaki, Toshiyuki
Crown ether catalyzed dehydrobromination of ω-(bromomethylene)adamantane (2) with t-BuOK provided a convenient and efficient method of generation of adamantylidenecarbene (1).In the presence of an appropriate olefin, 1 gave the corresponding adamantyliden
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(1968)
