852103-39-0Relevant academic research and scientific papers
Catalytic enantioselective allylation at the activated benzylic position of prochiral aryl cyano esters: Access to quaternary stereogenic centers
Nowicki, Audrey,Mortreux, André,Agbossou-Niedercorn, Francine
, p. 1617 - 1621 (2005)
Palladium catalyzed asymmetric allylic alkylation of prochiral aryl cyano esters has been carried out in the presence of various chiral ligands. The base and additives have been varied and allowed to produce the allyl derivative presenting a highly functi
Construction of quaternary carbon stereocentres: Catalytic enantioselective allylation assisted by a bimetallic catalytic system
Nowicki, Audrey,Mortreux, Andre,Agbossou-Niedercorn, Francine
, p. 1295 - 1298 (2007/10/03)
The asymmetric allylic alkylation of prochiral aryl cyano esters has been carried out in the presence of a bi-component catalytic system containing a palladium and a rhodium complex modified by phosphorus containing chiral auxiliaries. The allyl derivativ
