85219-48-3Relevant academic research and scientific papers
Studies on (XCN)2M(NCS)2Hg2(p-tolyl)2 and (XCN)2M(NCS)2Hg2-(α-naphthyl)2 and Their Complexes with Pyridine, Dimethyl Sulphoxide and 2,2'-Bipyridyl
Singh, P. P.,Atreya, Kshipra,Yadava, S. P.
, p. 376 - 381 (2007/10/02)
Bimetallic compounds of the formula (XCN)2M(NCS)2Hg2R2 and their complexes with pyridine (Py), dimethyl sulphoxide (DMSO) and 2,2'-bipyridyl (bipy) have been prepared and characterised by elemental analyses, molar conductance, molecular weight, magnetic moment, infrared and electronic spectral studies.These studies reveal that (XCN)2M(NCS)2Hg2R2 and their Py and DMSO adducts are monomeric while the 2,2'-bipyridyl complexes are cationic-anionic.The stereochemistry around Co(II) and Ni(II) ions is octahedral in all their compounds except in the case of (XCN)2MCo(NCS)2Hg2R2 where it is tetrahedral.
