852547-08-1Relevant academic research and scientific papers
Anodic electrochemistry of ferrocenylphosphine and ruthenocenylphosphine chalcogenide complexes and lewis acid adducts
Swartz, Brett D.,Nataro, Chip
, p. 2447 - 2451 (2005)
The anodic electrochemistry of a series of bidentate phosphine chalcogenides and bidentate phosphine Lewis acid adducts, both with a metallocene backbone, was examined in dichloromethane containing [NBu 4][PF6]. Oxidation of the ferrocene compounds dppfE 2 and dippfE2 (E = O, S, BH3, CH 3+) was reversible on the cyclic voltammetric (CV) time scale, while the oxidation of the dpprE2 compounds (E = O, S, BH 3) was irreversible; however, the oxidation of dppfSe2, dippfSe2, and dpprSe2 displayed an irreversible wave and the reduction of a follow-up product.
