852575-29-2Relevant academic research and scientific papers
Efficient unimolecular deprotonation of aniline radical cations
Dombrowski, Gary W.,Dinnocenzo, Joseph P.,Zielinski, Paul A.,Farid, Samir,Wosinska, Zofia M.,Gould, Ian R.
, p. 3791 - 3800 (2005)
Deprotonation of the radical cations of aromatic amines, such as anilines, generally occurs much more slowly than other fragmentation reactions. Here we report a stereoelectronic effect involving twisting of the anilino group out of the plane of the benze
