
Journal of Organic Chemistry p. 3791 - 3800 (2005)
Update date:2022-07-29
Topics:
Dombrowski, Gary W.
Dinnocenzo, Joseph P.
Zielinski, Paul A.
Farid, Samir
Wosinska, Zofia M.
Gould, Ian R.
Deprotonation of the radical cations of aromatic amines, such as anilines, generally occurs much more slowly than other fragmentation reactions. Here we report a stereoelectronic effect involving twisting of the anilino group out of the plane of the benze
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