852612-03-4

Basic information

• Product Name: C₂₂H₂₄Br₂O₁₀S₂
• Synonyms: C₂₂H₂₄Br₂O₁₀S₂
• CAS NO: 852612-03-4
• Molecular Weight: 672.367
• Mol File: 852612-03-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₂H₂₄Br₂O₁₀S₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₂H₂₄Br₂O₁₀S₂(852612-03-4)
• EPA Substance Registry System: C₂₂H₂₄Br₂O₁₀S₂(852612-03-4)

Safety Data

• Hazardous Substances Data: 852612-03-4(Hazardous Substances Data)

Upstream product

• 28224-74-0 1,3:4,6-di-O-benzylidene-2,5-di-O-methanesulfonyl-D-mannitol 

Downstream Products

• 130282-82-5 D_g-threo-dibenzoyloxy-hexadiene-(1.5) 
• 1069-23-4 (3R,4R)-1,5-hexadiene-3,4-diol 

Relevant articles and documents

Regioselective cleavage of the bis-benzylidene acetal of D-mannitol under oxidative and reductive conditions: A new approach to C2-symmetric chiral ligands

A highly regioselective oxidative cleavage of 1,3:4,6-di-O-benzylidene-d- mannitol was carried out using NBS and the resultant product was readily converted to the C2-symmetric chiral ligand, (R,R)-3,4-dihydroxy-1,5- hexadiene. On the other hand, reductive cleavage of 1,3:4,6-di-O-benzylidene-d- mannitol was achieved in a highly regioselective manner using BF 3?OEt2 and Et3SiH to give a highly functionalized benzyl ether, which was converted to a synthetically useful C2-symmetric bis-amino alcohol derivative.