85291-33-4Relevant articles and documents
CHEMISTRY OF KETENE ACETALS V. CATALYZED AND NON-CATALYZED (2+2)- AND (4+2)-CYCLOADDITIONS BETWEEN 1,2-DIKETONES AND KETENE ACETALS
Bakker, C. G.,Scheeren, J. W.,Nivard, R. J. F.
, p. 96 - 102 (2007/10/02)
Generally, 1,1-dimethoxypropene (CH3CH=C(OMe)2, 1b) yields only (2+2)-cycloadducts, viz. oxetanes (3) and bis-oxetanes (4), in reactions with 1,2-diketones; (4+2)-cycloaddition products, viz. dihydrodioxins (5), are not formed because of their thermodynam