6067-45-4

Basic information

• Product Name: Bis(4-nitrophenyl) diketone
• Synonyms: 1,2-Bis(4-nitrophenyl)ethane-1,2-dione;4,4'-Dinitrobenzil;Bis(4-nitrophenyl) diketone;1,2-bis(4-nitrophenyl)-1,2-Ethanedione
• CAS NO: 6067-45-4
• Molecular Formula: C₁₄H₈N₂O₆
• Molecular Weight: 300.22
• Mol File: 6067-45-4.mol
• Article Data: 21

Chemical Properties

• Melting Point: 213 °C
• Boiling Point: 532.3±35.0 °C(Predicted)
• Appearance: /
• Density: 1.471±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Bis(4-nitrophenyl) diketone(CAS DataBase Reference)
• NIST Chemistry Reference: Bis(4-nitrophenyl) diketone(6067-45-4)
• EPA Substance Registry System: Bis(4-nitrophenyl) diketone(6067-45-4)

Safety Data

• Hazardous Substances Data: 6067-45-4(Hazardous Substances Data)

Usage

General Description

Bis(4-nitrophenyl) diketone is a chemical compound that shares characteristics with both ketones and phenyl groups. It contains two 4-nitrophenyl groups and two ketone groups in its molecular structure. The presence of nitro groups imparts different properties to this chemical, such as being able to react with various other substances and potentially acting as a hydrogen acceptor. The actual use of this chemical is not widely elaborated in readily available literature as research on this specific compound is not extensive. The compound would require specific handling and safety measures due to its potential reactivity.

Upstream product

• 492-70-6 1,2-diphenyl-1,2-ethanediol 
• 555-16-8 4-nitrobenzaldehdye 
• 7697-37-2 nitric acid 
• 102034-64-0 2-benzoyloxy-1,2-bis(4-nitrophenyl)ethanone 
• 937-31-5 (4-Nitrophenyl)acetylene 
• 17763-80-3 para-nitrophenyl triflate 
• 636-98-6 p-nitrobenzene iodide 
• 2735-14-0 1,2-bis(4-nitrophenyl)acetylene 
• 122-04-3 4-nitro-benzoyl chloride 
• 108860-26-0 4-(p-nitrobenzoyloxy)-3,4-di(p-nitrophenyl)-1,1-diphenyl-2-azabuta-1,3-diene 
• 5466-94-4 4-Nitro-N-phenyl-benzimidoyl chloride 
• 14224-99-8 2-methyl-4,5-diphenyloxazole 
• 51130-02-0 2-benzoyloxy-2-(4-nitrophenyl)acetonitrile 
• 13295-04-0 1.2-bis(4-nitrophenyl)ethane-1,2-diol 

Downstream Products

• 57736-09-1 4.4'-dinitro-benzil-mono-seqtrans-oxime 
• 57736-09-1 4.4'-dinitro-benzil-mono-seqcis-oxime 
• 855293-17-3 4,4'-diamino-benzoin 
• 29602-15-1 4,4'-diaminobenzil 
• 88407-71-0 2,2,2-Trimethoxy-4,5-bis-(4-nitro-phenyl)-2λ⁵-[1,3,2]dioxaphosphole 
• 4100-98-5 1,1,2,2-Tetrafluor-1,2-bis-<4-nitro-phenyl>-aethan 
• 127631-81-6 2,2-Bis-(4-nitro-phenyl)-2H-imidazo[1,2-a]pyridin-3-one 
• 123351-51-9 3,4-dihydro-4-hydroxy-3-methyl-4,5-bis-(4-nitrophenyl)imidazole-2-thione 
• 85291-05-0 2,2,3,3-Tetramethoxy-5,6-bis-(4-nitro-phenyl)-2,3-dihydro-[1,4]dioxine 
• 101685-43-2 2,3-Bis-(4-nitro-phenyl)-quinolizinylium; bromide 
• 138841-97-1 4-Methyl-6,7-bis-(4-nitro-phenyl)-4H-1-oxa-4,5,8-triaza-anthracen-3-one 
• 138842-05-4 4-Ethyl-6,7-bis-(4-nitro-phenyl)-4H-1-oxa-4,5,8-triaza-anthracen-3-one 
• 138842-13-4 4-Allyl-6,7-bis-(4-nitro-phenyl)-4H-1-oxa-4,5,8-triaza-anthracen-3-one 
• 62-23-7 4-nitro-benzoic acid 

Relevant articles and documents

Sequentially Pd/Cu-Catalyzed Alkynylation-Oxidation Synthesis of 1,2-Diketones and Consecutive One-Pot Generation of Quinoxalines

We report a simple and efficient one-pot synthesis of 1,2-diketones by concatenation of two Pd/Cu-catalyzed processes: Pd0/CuI-catalyzed Sonogashira coupling of terminal alkynes with aryl (pseudo)halides furnishes internal alkynes, which are directly transformed by PdII/CuII-catalyzed Wacker-type oxidation with DMSO and oxygen as dual oxidants to furnish 1,2-diketones. With this efficient, catalyst economical process, various aryl iodides and triflates are efficiently transformed in high yields into symmetrically and unsymmetrically substituted 1,2-diketones with various functional groups. This process can be readily extended to a consecutive one-pot synthesis of quinoxalines in a diversity-oriented fashion.

Synthesis of smart bimetallic nano-Cu/Ag@SiO2 for clean oxidation of alcohols

Here, we have demonstrated the synthesis and characterization of silica supported bimetallic copper/silver nanoparticles (Cu/Ag@SiO2 NPs) and their application in the clean oxidation of benzoins/benzyl alcohols in the presence of tert-butyl hydroperoxide as a mild oxidant. All the reactions were very fast (4 h) and high yielding (95-99%), and the Cu/Ag@SiO2 NPs were very stable under the reaction conditions. The catalyst was recovered simply by filtration and reused eight times without loss of its catalytic performance.

O-Benzoyl pyridine aldoxime and amidoxime derivatives: Novel efficient DNA photo-cleavage agents

O-Benzoyl derivatives of meta-, ortho- and para-pyridine aldoximes and amidoximes are novel efficient DNA photo-cleavage agents. In particular O-p-nitro-benzoyl derivatives 4, 8 and 15 were effective at concentrations as low as 1 μM. Both aldoximes and amidoximes were active under aerobic and anaerobic conditions, with a double-stranded to single-stranded DNA cleavage ratio of up to 1. These results give prospects for multiple applications, including phototherapeutic treatment of solid tumors. This journal is