85318-95-2Relevant academic research and scientific papers
Pd(II)-Catalyzed cyclogeneration of carbocations: Subsequent rearrangement and trapping under oxidative conditions
Koh, Jeong Hwan,Mascarenhas, Cheryl,Gagné, Michel R.
, p. 7405 - 7410 (2004)
A catalytic oxidative polycyclization reaction initiated by the carbocyclization of 1,5-dienes with Pd(II) is reported. Trapping of a putative carbocation with suitable functional groups (phenols, alkenes, alcohols, sulfonamide), or rearrangement protocol
Perhydroazulenes. 6. 4-Keto Derivatives with Bridgehead Methyl Substituents
House, Herbert O.,Nomura, Glenn S.,VanDerveer, Don,Wissinger, Jane E.
, p. 2408 - 2416 (2007/10/02)
The two 9-methyl stereoisomers 3 and 4 and the two 10-methyl stereoisomers 8 and 9 of 4-ketoperhydroazulene have been prepared and fully characterized by means of spectra, analyses, and crystal structures.Several routes, including the selective methylatio
