85319-24-0Relevant academic research and scientific papers
Enones with Strained Double Bonds. 8. The Bicyclooctane Systems
House, Herbert O.,Haack, John L.,McDaniel, William C.,VanDerveer, Don
, p. 1643 - 1654 (1983)
The bicyclic enones bicyclooct-1-en-3-one (4) and 1-methylbicyclooct-5(6)-en-7-one (5) have been generated from various precursors and trapped by the addition of nucleophiles such as MeOH, PhSeH, or H2O.The bridgehead enone 5 has also been trapped as its cycloadduct 31 with furan.Pyrolysis of this cycloadduct 31 reformed the bridgehead enone 5 that was trapped as the cycloadduct 32.Related bridgehead enones 35 and 47 have also been generated as intermediates leading to products with bridgehead methoxy substituents.
