Journal of Organic Chemistry p. 1643 - 1654 (1983)
Update date:2022-08-04
Topics:
House, Herbert O.
Haack, John L.
McDaniel, William C.
VanDerveer, Don
The bicyclic enones bicyclo<3.2.1>oct-1-en-3-one (4) and 1-methylbicyclo<3.2.1>oct-5(6)-en-7-one (5) have been generated from various precursors and trapped by the addition of nucleophiles such as MeOH, PhSeH, or H2O.The bridgehead enone 5 has also been trapped as its cycloadduct 31 with furan.Pyrolysis of this cycloadduct 31 reformed the bridgehead enone 5 that was trapped as the cycloadduct 32.Related bridgehead enones 35 and 47 have also been generated as intermediates leading to products with bridgehead methoxy substituents.
View MoreZhejiang Golden-Shell Pharmaceutical Co.,Ltd.
Contact:+86-576-87501888 / 87501988
Address:No.89 Zhongxing Road. Li'ao, Yuhuan, Zhejiang, China
Jinzhou Jiutai Pharmaceutical Co.,Ltd
Contact:+86-0416-5179890
Address:No.41, Taianli, Taihe District, Jinzhou, Liaoning
jiangsu hualin chemical co.,ltd.
Contact:86-25-87787402
Address:jaingsu,china
CGeneTech (Suzhou, China) Co., Ltd.
Contact:+86-512-62956962
Address:Room 101，Bld C11,218 Xinghu Rd.,Suzhou industrial Park
Shanghai Yuanye Bio-Technology Co., Ltd.
website:http://www.shyuanye.com
Contact:+86-21-61845781
Address:Building 6, No. 465, Changta Road,Songjiang District,Shanghai,China
Doi:10.1002/anie.201800595
(2018)Doi:10.1039/DT9830000245
(1983)Doi:10.1021/ja01260a011
(1942)Doi:10.1016/S0022-1139(00)81116-1
(1983)Doi:10.1021/jo01373a022
(1954)Doi:10.1021/acs.jmedchem.9b00838
(2019)
