853308-49-3Relevant academic research and scientific papers
Efficient synthesis of oligosaccharyl 1,2-O-orthoesters from n-pentenyl glycosides and application to the pentaarabinofuranoside of the mycobacterial cell surface
Thadke, Shivaji A.,Hotha, Srinivas
, p. 9914 - 9920 (2015/01/08)
Complex oligosaccharide syntheses employ the use of more than one glycosyl donor and hence, methods for the interconversion of glycosyl donors are highly valuable for the overall synthesis plan. Herein, n-pentenyl glycosides are efficiently converted to g
Gold mediated glycosylations: Selective activation of propargyl 1,2-orthoesters in the presence of aglycones containing a propargyl moiety
Sureshkumar, Gopalsamy,Hotha, Srinivas
supporting information; experimental part, p. 4282 - 4284 (2009/03/12)
Selective activation of propargyl 1,2-orthoesters in the presence of propargyl glycosides and propargyl ethers was studied; a catalytic amount of AuBr3 activated the propargyloxy group of the 1,2-orthoester thereby giving access to disaccharide
Ionic liquid [bmim]PF6-mediated synthesis of 1,2-orthoesters of carbohydrates and the glycosidation reactions of 4-pentenyl orthoesters
Anas, Saithalavi,Sajisha, Valiyaveetil Sanjayan,Rajan, Rani,Kumaran, Rajasekaran Thirumalai,Radhakrishnan, Kokkuvayil Vasu
, p. 553 - 560 (2008/02/11)
A facile synthesis of the 1,2-orthoesters of carbohydrates in the ionic liquid [bmim]PF6 without a quaternary ammonium salt like tetrabutylammonium iodide, is described. The glycosidation reactions of 4-pentenyl orthoesters (NPOEs) with differe
A facile and eco-friendly method for the synthesis of 1,2-orthoesters of carbohydrates in ionic liquid
Radhakrishnan,Sajisha,Chacko, Jessy Maria
, p. 997 - 999 (2007/10/03)
A facile method for the synthesis of 1,2-orthoesters of carbohydrates in ionic liquid [bmim]PF6 is described. The method described herein is simpler, eco-friendly and avoids the addition of quaternary ammonium salts as promoters.
