85335-71-3

Basic information

• Product Name: Thiocarbonic acid O-[(8S,9S,10R,13R,14S,17R)-17-((R)-1,5-dimethyl-hexyl)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl] ester O-phenyl ester
• Synonyms: Thiocarbonic acid O-[(8S,9S,10R,13R,14S,17R)-17-((R)-1,5-dimethyl-hexyl)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl] ester O-phenyl ester
• CAS NO: 85335-71-3
• Molecular Weight: 522.836
• Mol File: 85335-71-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Thiocarbonic acid O-[(8S,9S,10R,13R,14S,17R)-17-((R)-1,5-dimethyl-hexyl)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl] ester O-phenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Thiocarbonic acid O-[(8S,9S,10R,13R,14S,17R)-17-((R)-1,5-dimethyl-hexyl)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl] ester O-phenyl ester(85335-71-3)
• EPA Substance Registry System: Thiocarbonic acid O-[(8S,9S,10R,13R,14S,17R)-17-((R)-1,5-dimethyl-hexyl)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl] ester O-phenyl ester(85335-71-3)

Safety Data

• Hazardous Substances Data: 85335-71-3(Hazardous Substances Data)

Upstream product

• 57-88-5 cholesterol 
• 1005-56-7 phenylcarbonochloridothioate 
• 765935-41-9 cholesterol 

Downstream Products

• 570-74-1 cholest-5-ene 
• 910-31-6 cholesteryl chloride 

Relevant articles and documents

Evaluation of cyclopentyl methyl ether (CPME) as a solvent for radical reactions

We have explored the potential of cyclopentyl methyl ether (CPME) as a solvent for radical reactions. Hydrostannation, hydrosilylation, hydrothiolation, and tributyltin hydride mediated reductions were successfully carried out in CPME. GC-MS analysis indicated that CPME degraded into methyl pentanoate, cyclopentanone, 2-cyclopenten-1-ol, and cyclopentanol under thermal radical conditions, albeit only slightly. We also achieved radical-containing one-pot reactions in CPME as a demonstration of its applicability to multi-step reactions.

Radical cation reactions associated with the thiocarbonyl group

The radical cation reactions of different thiocarbonyl compounds were examined. Compounds 7, 8, 11, 14 and 18 underwent a radical cation fragmentation in a photoinduced electron transfer (PET) reaction, in the presence of tris(4-bromophenyl)aminium hexachloroantimonate.

Smooth and Efficient Deoxygenation of Secondary Alcohols. A General Procedure for the Conversion of Ribonucleosides to 2'-Deoxynucleosides

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