853399-79-8Relevant academic research and scientific papers
Iodine-promoted silylation of alcohols with silyl chlorides. Synthetic and mechanistic studies
Bartoszewicz, Agnieszka,Kalek, Marcin,Stawinski, Jacek
, p. 8843 - 8850 (2008)
An efficient silylating system for 1°, 2°, and 3° alcohols, consisting of a silyl chloride/N-methylimidazole/iodine, was developed. Synthetic and mechanistic aspects of this new reagent system, and particularly the role of iodine were investigated in detail using 1H NMR spectroscopy.
Stereoselective Synthesis of 1,1′-Disaccharides by Organoboron Catalysis
Izumi, Sanae,Kobayashi, Yusuke,Takemoto, Yoshiji
supporting information, p. 14054 - 14059 (2020/06/10)
The highly stereoselective synthesis of 1,1′-disaccharides was achieved by using 1,2-dihydroxyglycosyl acceptors and glycosyl donors in the presence of a tricyclic borinic acid catalyst. In this reaction, the complexation of the diols and the catalyst is
Formal synthesis of (+)-varitriol. Application of Pd(II)/Cu(II)-catalysed bicyclisation of unsaturated polyols
Pailk, Miroslav,Karlubiková, Olga,Lackovková, Daniela,Lásiková, Angelika,Gracza, Tibor
experimental part, p. 5244 - 5249 (2010/08/13)
A formal and improved synthesis of natural (+)-varitriol from D-glucose and dimethyl L-tartrate, respectively, are reported. The key steps are the Pd(II)Cu(II)-catalysed bicyclisation of O-benzyl protected triols L-xylo-15 and L-xylo-15/L-lyxo-15, respect
