85355-84-6Relevant academic research and scientific papers
Homoallylic Alcohols from Samarium Diiodide-mediated Coupling of Allylic Sulfones with Carbonyl Compounds
Clayden, Jonathan,Julia, Marc
, p. 2261 - 2262 (2007/10/02)
Reduction of allylic sulfones with samarium diiodide gives allylsamarium species which react in situ with carbonyl compounds, yielding homoallylic alcohols.
Electrogenerated Zinc as the Catalyst in the Allylation of Carbonyl Compounds. Direct Synthesis of α-Methylene-γ-Lactones
Rollin, Y.,Derien, S.,Dunach, E.,Gebehenne, C.,Perichon, J.
, p. 7723 - 7732 (2007/10/02)
The electroreduction of a catalytic amount of ZnBr2 in acetonitrile provided a active Zn*, able to catalyze the reductive coupling of allyl bromides and chlorides with carbonyl compounds with high regioselectivity.Substituted α-methylene γ-lactones were o
SmCl3-CATALYSED ELECTROCHEMICAL REDUCTIVE ALLYLATION OF KETONES
Hebri, Hassan,Dunach, Elisabet,Perichon, Jacques
, p. 1475 - 1478 (2007/10/02)
A series of homoallylic alcohols was prepared in moderate to good yields from allyl chlorides and ketones, through an electrochemical method using SmCl3 as the catalyst precursor.The electrosyntheses were carried out in undivided cells fitted with a consumable magnesium anode.
