85356-32-7

Upstream product

• 55619-31-3 Cyclohexyl-[3-imino-2-methyl-1-phenyl-3-p-tolyl-prop-(Z)-ylidene]-amine 
• 117708-69-7 (1R,2R,4S)-2-((S)-1-Benzyloxy-ethyl)-5-methyl-1,6-diphenyl-4-p-tolyl-1,2,3,4-tetrahydro-pyrimidine 
• 138356-05-5 3-imino-1,N-diphenyl-2-methyl-3-(p-tolyl)prop-1-enylamine 
• 138356-07-7 (2R*,6S*)-5-Methyl-2,3,4-triphenyl-6-p-tolyl-1,2,3,6-tetrahydropyrimidine 
• 85356-26-9 [3-Imino-2-methyl-1-phenyl-3-p-tolyl-prop-(Z)-ylidene]-p-tolyl-amine 

Relevant academic research and scientific papers

Stereoselective Synthesis of 1,3-Amino Alcohols and 1,3-Amino Ketones

syn,anti-N-Alkyl-1,3-amino alcohols 2 with three chiral centers are synthesized with high stereoselectivity by reduction of the corresponding anti-N-acylamino ketones 1 with LiAlH4/TiCl4.The intermediate N-acylamino alcohols 3 can be isolated when DIBALH/

AZADIENE DERIVATIVES AS SYNTHETIC INTERMEDIATES

The applicability 4-amino-1-azabutadienes 1 in synthesis of five-, six-, and eight-membered ring heterocycles is demonstrated; several open-chain compounds have also been diastereo- or enantio-selectively prepared.The synthesis and reactivity of both neut

Reduction of 1,3-Diimines. A New and General Method of Synthesis of γ-Diamines, β-Amino Ketones, and Derivatives with Two and Three Chiral Centers

1,3-Diimes 1 are easily reduced with Na/i-PrOH to afford unsymmetrical N-substituted γ-diamines 8 in nearly quantitative yields.Since three chiral centers are generated, compounds 8 are isolated as a mixture of diastereoisomers which are easily separated.