85359-61-1Relevant articles and documents
PHOTOOXYGENATION OF 2',4,4'-TRIHYDROXYCHALCONE: IDENTITY WITH PRODUCTS FROM ENZYMIC OXIDATION
Wong, Edmon
, p. 1544 - 1545 (2007/10/02)
The dioxetane derivative of 2',4,4'-trihydroxychalcone, previously known as a product from peroxidase-catalysed oxidation, has now been detected in the dye-sensitized photooxygenation of the same chalcone and shown to be accountable for the host of other products formed. - Key Word Index: Dioxetanes; chalcones; photooxygenation.
Chalaurenol: a Novel Product from Enzymic Oxidation of 2',4,4'-Trihydroxychalcone
Begley, Michael J.,Crombie, Leslie,London, Martin,Savin, John,Whiting, Donald A.
, p. 1319 - 1321 (2007/10/02)
Peroxidase enzymes from various sources convert 2',4,4'-trihydroxychalcone (1) into the novel quinol ether of 2-formyl-6-hydroxycoumaranone (6), the structure of which was determined by X-ray diffraction; a biosynthetic pathway is suggested and capillarisin (11) may arise by a similar route.