85365-59-9

Upstream product

• 85365-61-3 racemic 5(R)-1-aza-4(R)-carboxy-6(R)-hydroxy-4(R)-(phenylseleno)bicyclo<3.3.0>octane lactone 
• 5707-04-0 Phenylselenyl chloride 
• 85319-62-6 1-aza-4-(1,3-dithian-2-ylidene)-6(S)-(acetyloxy)bicyclo<3.3.0>octan-8-one 
• 98634-55-0 racemic 5(R)-1-aza-4-(1,3-dithian-2-ylidene)bicyclo<3.3.0>octan-6-one 
• 98634-54-9 5(R)-1-aza-4-(1,3-dithian-2-ylidene)-6(S)-hydroxybicyclo<3.3.0>octane 
• 1666-13-3 diphenyl diselenide 
• 45847-99-2 racemic 5(R)-1-aza-4(S)-carboxy-6(R)-hydroxybicyclo<3.3.0>octane lactone 
• 85365-60-2 1-Benzyl-1-aza-cyclooctan-5-on-4-carbonsaeureethylester 
• 85365-57-7 ethyl (+/-)-1-hydroxy-2,3,5,6-tetrahydro-1H-pyrrolizine-7-carboxylate 
• 41646-10-0 2,3,5,6-Tetrahydro-1H-pyrrolizin-7-carbonsaeure-ethylester 

Relevant academic research and scientific papers

A CONVENIENT SYNTHESIS OF (+/-)-RETRONECINE

Retronecine (1), the necine base of physiologically active pyrrolizidine alkaloids was synthesized in racemic form from ethyl 2,3,5,6-tetrahydro-1H-pyrrolizine-7-carboxylate (2) in five steps.

Enantioselective Synthesis of Seven Pyrrolizidine Diols from a Single Precursor

The enantioselective synthesis of seven pyrrolizidine diols has been accomplished from a single, readily available intermediate.The key step of this general scheme involves an acetoxy-directed acyliminium ion-ketene dithioacetal cationic cyclization to gi