853732-44-2Relevant academic research and scientific papers
Preparation of copper ion complexes of sterically congested diaryldiazomethanes having a pyridine ligand and characterization of their photoproducts
Itoh, Tetsuji,Matsuno, Masayoshi,Kamiya, Eiko,Hirai, Katsuyuki,Tomioka, Hideo
, p. 7078 - 7093 (2007/10/03)
To realize fairly stable high-spin polycarbenes by utilizing heterospin systems comprising 2p spins of organic radicals and 3d spins of magnetic metal ions, we prepared dianthryldiazomethanes having two pyridyl groups at the 2,2′- or 2,7-positions, that i
A tris(carbene) constructed with stable triplet carbene units
Tsuchiya, Yoko,Matsuno, Masayoshi,Itoh, Tetsuji,Hirai, Katsuyuki,Tomioka, Hideo
, p. 2037 - 2050 (2007/10/03)
Bis[10-(4-t-butyl-2,6-dimethylphenyl)-9-anthryl]diazomethane, which can generate a fairly stable triplet carbene that can survive for even a week in solution at room temperature, was shown to be stable enough to undergo a Sonogashira coupling reaction. Th
