85374-87-4Relevant academic research and scientific papers
The first unequivocal evidence of the reacting electrophile in aromatic acylation reactions
Effenberger, Franz,Eberhard, Joachim K.,Maier, Andreas H.
, p. 12572 - 12579 (2007/10/03)
The acylation of aromatic compounds with aroyl triflates can be performed in organic solvents (1,2-dichloroethane) without Friedel-Crafts catalysts. These reaction conditions allow kinetic investigations of the reaction in homogeneous solution. From rate
Carboxylic Trifluoromethanesulfonic and Methanesulfonic Anhydrides, Synthesis and Dissociation Tendency
Effenberger, Franz,Epple, Gerhard,Eberhard, Joachim K.,Buehler, Ulrich,Sohn, Erich
, p. 1183 - 1194 (2007/10/02)
Carbonyl chlorides 1 react with silver trifluoromethanesulfonate (2) and silver methanesulfonate (6) to give carboxylic trifluoromethanesulfonic anhydrides 3 and carboxylic methanesulfonic anhydrides 7, resp., in good yields; the anhydrides 3 may be synth
