85375-07-1Relevant academic research and scientific papers
Anodic Preparation of N-(2,2,2-Trifluoroethylidene)sulfenamides and Their Application to the Synthesis of Trifluoromethylated Amines, Aminoketone, and Aminoalkanoates
Fuchigami, Toshio,Ichikawa, Shinji,Konno, Akinori
, p. 2405 - 2408 (1992)
N-(2,2,2-Trifluoroethylidene)sulfenamides (trifluoromethylated sulfenimines) were easily prepared in one step by anodic oxidation of 2,2,2-trifluoroethylamine and diaryl disulfides in MeCN/Et4NClO4 using MgBr2 as a redox mediator.The sulfenimines were hig
