85414-01-3Relevant academic research and scientific papers
One-pot synthesis of N-tert-butyl amides from alcohols, ethers and esters using ZnCl2/SiO2 as a recyclable heterogeneous catalyst
Tamaddon, Fatemeh,Tavakoli, Fatemeh
experimental part, p. 52 - 55 (2011/04/24)
ZnCl2/SiO2 has been found to be an efficient and reusable catalyst for conversion of alcohols, ethers and esters to corresponding amides via the Ritter reaction in high yield. It was found that benzonitrile reacted with tert-butyl acetate faster than the other sources of tert-butyl carbocation.
An unusual radical smiles rearrangement
Bacque, Eric,El Qacemi, Myriem,Zard, Samir Z.
, p. 3817 - 3820 (2007/10/03)
(Chemical Equation Presented) Radicals derived from N-(α-xanthyl) acetanilides or N-(α-xanthyl)acetylaminopyridines possessing a substituent next to the nitrogen undergo a hitherto undocumented Smiles rearrangement proceeding through a four-membered ring.
